10 research outputs found

    An investigation into the fabrication parameters of screen-printed capacitive sensors on e-textiles

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    [EN] The design and development of textile-based capacitive sensors requires the implementation of textile capacitors with a determined capacitance. One of the main techniques to obtain these sensors is the screen-printing of conductive and dielectric inks on textiles. This paper investigates the fabrication parameters that have the most influence when designing and implementing a screen-printed capacitive sensor. In this work, a textile has been used directly as the dielectric part, influencing sensitively the value of the permittivity and the thickness of the dielectric of the capacitor. These are two fundamental parameters for the estimation of its capacitance. The choice of the conductive ink, its viscosity and solid content, as well as printing parameters, such as printing direction, also impact on the manner for obtaining the electrodes of the capacitive sensor. Although the resulting electrodes do not represent an important parameter for the estimation of the capacitance, it determines the selection of fabrics that can be printed. As a result of the investigation, the paper provides a guideline to choose the materials, such as fabrics or inks, as well as the printing parameters, to implement e-textile applications based on projected capacitive technologies. The experiments carried out on different fabrics and inks have provided results with capacities of less than 60 pF, the limit where the sensors based on capacitive technologies are located.The authors disclosed receipt of the following financial support for the research, authorship and/or publication of this article: This work was supported by the Conselleria d'Economia Sostenible, Sectors Productius i Treball, through IVACE (Instituto Valenciano de Competitividad Empresarial) and cofounded by ERDF funding from the European Union (Application no. IMAMCI/2019/1). This work was also supported by the Spanish Government/FEDER funds (RTI2018-100910-B-C43) (MINECO/FEDER).Ferri, J.; Llinares Llopis, R.; Moreno, J.; Lidon-Roger, JV.; Garcia-Breijo, E. (2020). An investigation into the fabrication parameters of screen-printed capacitive sensors on e-textiles. Textile Research Journal. 90(15-16):1749-1769. https://doi.org/10.1177/0040517519901016S174917699015-16Gonçalves, C., Ferreira da Silva, A., Gomes, J., & Simoes, R. (2018). Wearable E-Textile Technologies: A Review on Sensors, Actuators and Control Elements. Inventions, 3(1), 14. doi:10.3390/inventions3010014Mostafalu, P., Tamayol, A., Rahimi, R., Ochoa, M., Khalilpour, A., Kiaee, G., … Khademhosseini, A. (2018). Smart Bandage for Monitoring and Treatment of Chronic Wounds. Small, 14(33), 1703509. doi:10.1002/smll.201703509Shi, H., Zhao, H., Liu, Y., Gao, W., & Dou, S.-C. (2019). Systematic Analysis of a Military Wearable Device Based on a Multi-Level Fusion Framework: Research Directions. Sensors, 19(12), 2651. doi:10.3390/s19122651Kim, K., Jung, M., Jeon, S., & Bae, J. (2019). Robust and scalable three-dimensional spacer textile pressure sensor for human motion detection. Smart Materials and Structures, 28(6), 065019. doi:10.1088/1361-665x/ab1adfFerri, J., Perez Fuster, C., Llinares Llopis, R., Moreno, J., & Garcia‑Breijo, E. (2018). Integration of a 2D Touch Sensor with an Electroluminescent Display by Using a Screen-Printing Technology on Textile Substrate. Sensors, 18(10), 3313. doi:10.3390/s18103313De Vos, M., Torah, R., Glanc-Gostkiewicz, M., & Tudor, J. (2016). A Complex Multilayer Screen-Printed Electroluminescent Watch Display on Fabric. Journal of Display Technology, 12(12), 1757-1763. doi:10.1109/jdt.2016.2613906Lin, X., & Seet, B.-C. (2017). Battery-Free Smart Sock for Abnormal Relative Plantar Pressure Monitoring. IEEE Transactions on Biomedical Circuits and Systems, 11(2), 464-473. doi:10.1109/tbcas.2016.2615603Ejupi, A., & Menon, C. (2018). Detection of Talking in Respiratory Signals: A Feasibility Study Using Machine Learning and Wearable Textile-Based Sensors. Sensors, 18(8), 2474. doi:10.3390/s18082474Polanský, R., Soukup, R., Řeboun, J., Kalčík, J., Moravcová, D., Kupka, L., … Hamáček, A. (2017). A novel large-area embroidered temperature sensor based on an innovative hybrid resistive thread. Sensors and Actuators A: Physical, 265, 111-119. doi:10.1016/j.sna.2017.08.030Komazaki, Y., & Uemura, S. (2019). Stretchable, printable, and tunable PDMS-CaCl2 microcomposite for capacitive humidity sensors on textiles. Sensors and Actuators B: Chemical, 297, 126711. doi:10.1016/j.snb.2019.126711Ng, C. L., & Reaz, M. B. I. (2019). Evolution of a capacitive electromyography contactless biosensor: Design and modelling techniques. Measurement, 145, 460-471. doi:10.1016/j.measurement.2019.05.031Ferri, J., Lidón-Roger, J., Moreno, J., Martinez, G., & Garcia-Breijo, E. (2017). A Wearable Textile 2D Touchpad Sensor Based on Screen-Printing Technology. Materials, 10(12), 1450. doi:10.3390/ma10121450Atalay, O. (2018). Textile-Based, Interdigital, Capacitive, Soft-Strain Sensor for Wearable Applications. Materials, 11(5), 768. doi:10.3390/ma11050768Yongsang Kim, Hyejung Kim, & Hoi-Jun Yoo. (2010). Electrical Characterization of Screen-Printed Circuits on the Fabric. IEEE Transactions on Advanced Packaging, 33(1), 196-205. doi:10.1109/tadvp.2009.2034536Lee, W. J., Park, J. Y., Nam, H. J., & Choa, S.-H. (2019). The development of a highly stretchable, durable, and printable textile electrode. Textile Research Journal, 89(19-20), 4104-4113. doi:10.1177/0040517519828992Chatterjee, K., Tabor, J., & Ghosh, T. K. (2019). Electrically Conductive Coatings for Fiber-Based E-Textiles. Fibers, 7(6), 51. doi:10.3390/fib7060051Gu, J. F., Gorgutsa, S., & Skorobogatiy, M. (2010). Soft capacitor fibers using conductive polymers for electronic textiles. Smart Materials and Structures, 19(11), 115006. doi:10.1088/0964-1726/19/11/115006Khan, S., Lorenzelli, L., & Dahiya, R. S. (2015). Technologies for Printing Sensors and Electronics Over Large Flexible Substrates: A Review. IEEE Sensors Journal, 15(6), 3164-3185. doi:10.1109/jsen.2014.2375203Zhang, Q., Wang, Y. L., Xia, Y., Zhang, P. F., Kirk, T. V., & Chen, X. D. (2019). Textile‐Only Capacitive Sensors for Facile Fabric Integration without Compromise of Wearability. Advanced Materials Technologies, 4(10), 1900485. doi:10.1002/admt.201900485Mukherjee, P. K. (2018). Dielectric properties in textile materials: a theoretical study. The Journal of The Textile Institute, 110(2), 211-214. doi:10.1080/00405000.2018.1473710Sadi, M. S., Yang, M., Luo, L., Cheng, D., Cai, G., & Wang, X. (2019). Direct screen printing of single-faced conductive cotton fabrics for strain sensing, electrical heating and color changing. Cellulose, 26(10), 6179-6188. doi:10.1007/s10570-019-02526-

    Screen-printed Organic Electrochemical Transistors for the detection of ascorbic acid in food

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    [EN] Methods traditionally used for ascorbic acid (AA) detection in food are often expensive and complex, making them unsuitable for day-to-day determinations. In this work, we report on the use of all- PEDOT:PSS Organic Electrochemical Transistors (OECTs) for fast, simple and low-cost determination of AA in food. The performance of these OECTs was tested first with in lab-prepared solutions of AA with different concentrations. The effect of the geometry on the transistors performance for AA sensing was also investigated by comparing the response of two OECTs with different channel and gate areas ratio (g), in terms of current modulation, sensitivity, background signal and limit of detection (LOD). OECTs with smaller gate electrode than the channel (large g) show the best performance for AA sensing: these devices display smaller background signal, higher sensitivity, larger modulation and better LOD value (80.10^-6 M). Since the AA content in food rich in Vitamin C is in the mM range, these transistors can be considered sensitive enough for quantitatively monitoring AA in food. In order to demonstrate the reliability of the proposed sensors in real food samples, the response of these transistors was additionally measured in a commercial orange juice. The amount of AA obtained with the OECTs is in good agreement with that determined by HPLC and with values reported in the literature for orange juices. Furthermore, these OECTs can be considered promising candidates for the selective detection of AA in the presence of other interfering antioxidants.This work was supported by Spanish Government/FEDER funds (grant number MAT2015-64139-C4-3-R (MINECO/FEDER)) and Generalitat Valenciana funds (grant number AICO/2015/103).Contat-Rodrigo, L.; Pérez Fuster, C.; Lidon-Roger, JV.; Bonfiglio, A.; Garcia-Breijo, E. (2017). Screen-printed Organic Electrochemical Transistors for the detection of ascorbic acid in food. Organic Electronics. 45:89-96. https://doi.org/10.1016/j.orgel.2017.02.03789964

    Comparison of E-Textile Techniques and Materials for 3D Gesture Sensor with Boosted Electrode Design

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    [EN] There is an interest in new wearable solutions that can be directly worn on the curved human body or integrated into daily objects. Textiles offer properties that are suitable to be used as holders for electronics or sensors components. Many sensing technologies have been explored considering textiles substrates in combination with conductive materials in the last years. In this work, a novel solution of a gesture recognition touchless sensor is implemented with satisfactory results. Moreover, three manufacturing techniques have been considered as alternatives: screen-printing with conductive ink, embroidery with conductive thread and thermosealing with conductive fabric. The main critical parameters have been analyzed for each prototype including the sensitivity of the sensor, which is an important and specific parameter of this type of sensor. In addition, user validation has been performed, testing several gestures with different subjects. During the tests carried out, flick gestures obtained detection rates from 79% to 89% on average. Finally, in order to evaluate the stability and strength of the solutions, some tests have been performed to assess environmental variations and washability deteriorations. The obtained results are satisfactory regarding temperature and humidity variations. The washability tests revealed that, except for the screen-printing prototype, the sensors can be washed with minimum degradation.This work was supported by the Spanish Government/FEDER funds (RTI2018-100910-B-C43) (MINECO/FEDER). The work presented is also funded by the Conselleria d'Economia Sostenible, Sectors Productius i Treball, through IVACE (Instituto Valenciano de Competitividad Empresarial) and cofounded by ERDF funding from the EU. Application No.: IMAMCI/2020/1Ferri Pascual, J.; Llinares Llopis, R.; Martinez, G.; Lidon-Roger, JV.; Garcia-Breijo, E. (2020). Comparison of E-Textile Techniques and Materials for 3D Gesture Sensor with Boosted Electrode Design. Sensors. 20(8):1-19. https://doi.org/10.3390/s20082369S11920

    Textile Concentric Ring Electrodes for ECG Recording Based on Screen-Printing Technology

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    [EN] Among many of the electrode designs used in electrocardiography (ECG), concentric ring electrodes (CREs) are one of the most promising due to their enhanced spatial resolution. Their development has undergone a great push due to their use in recent years; however, they are not yet widely used in clinical practice. CRE implementation in textiles will lead to a low cost, flexible, comfortable, and robust electrode capable of detecting high spatial resolution ECG signals. A textile CRE set has been designed and developed using screen-printing technology. This is a mature technology in the textile industry and, therefore, does not require heavy investments. Inks employed as conductive elements have been silver and a conducting polymer (poly (3,4-ethylenedioxythiophene) polystyrene sulfonate; PEDOT: PSS). Conducting polymers have biocompatibility advantages, they can be used with flexible substrates, and they are available for several printing technologies. CREs implemented with both inks have been compared by analyzing their electric features and their performance in detecting ECG signals. The results reveal that silver CREs present a higher average thickness and slightly lower skin-electrode impedance than PEDOT: PSS CREs. As for ECG recordings with subjects at rest, both CREs allowed the uptake of bipolar concentric ECG signals (BC-ECG) with signal-to-noise ratios similar to that of conventional ECG recordings. Regarding the saturation and alterations of ECGs captured with textile CREs caused by intentional subject movements, silver CREs presented a more stable response (fewer saturations and alterations) than those of PEDOT: PSS. Moreover, BC-ECG signals provided higher spatial resolution compared to conventional ECG. This improved spatial resolution was manifested in the identification of P1 and P2 waves of atrial activity in most of the BC-ECG signals. It can be concluded that textile silver CREs are more suitable than those of PEDOT: PSS for obtaining BC-ECG records. These developed textile electrodes bring the use of CREs closer to the clinical environment.Grant from the Ministerio de Economia y Competitividad y del Fondo Europeo de Desarrollo Regional. DPI2015-68397-R (MINECO/FEDER). This work was also supported by the Spanish Government/FEDER funds (grant number MAT2015-64139-C4-3-R (MINECO/FEDER)).Lidon-Roger, JV.; Prats-Boluda, G.; Ye Lin, Y.; Garcia Casado, FJ.; Garcia-Breijo, E. (2018). Textile Concentric Ring Electrodes for ECG Recording Based on Screen-Printing Technology. Sensors. 18(1):300-314. https://doi.org/10.3390/s18010300S30031418

    A comparative analysis of printing techniques by using an active concentric ring electrode for bioelectrical recording

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    Purpose This paper aims to present a comparison between three types of manufacturing techniques, namely, screen-printed, inkjet and gravure, using different types of inks, for the implementation of concentric ring electrodes which permit estimation of Laplacian potential on the body surface. Design/methodology/approach Flexible concentric ring electrodes not only present lower skin electrode contact impedance and lower baseline wander than rigid electrodes but are also less sensitive to interference and motion artefacts. The above three techniques allow printing of conductive inks on flexible substrates, and with this work, the authors aim to study which is the best technique and ink to obtain the best electrode response. Findings From the results obtained regarding ink thickness, resistivity, electrode resistance and other performance parameters derived from electrocardiographic signal recording tests, it can be said that concentric electrodes using the screen-printing and inkjet techniques are suitable for non-invasive bioelectric signal acquisition. Originality/value The development of new types of inks and substrates for the electronics industry and the adaptation of new manufacturing techniques allow for an improvement in the development of electrodes and sensors.This work was financially supported by the Spanish Government and European FEDER funds (MAT2012-38429-C04-04).García Breijo, E.; Prats Boluda, G.; Lidon-Roger, JV.; Ye Lin, Y.; Garcia Casado, FJ. (2015). A comparative analysis of printing techniques by using an active concentric ring electrode for bioelectrical recording. Microelectronics International. 32(2):103-107. https://doi.org/10.1108/MI-03-2015-0021S103107322Besio, W., Aakula, R., Koka, K., & Dai, W. (2006). Development of a Tri-polar Concentric Ring Electrode for Acquiring Accurate Laplacian Body Surface Potentials. Annals of Biomedical Engineering, 34(3), 426-435. doi:10.1007/s10439-005-9054-8Besio, W., & Chen, T. (2007). Tripolar Laplacian electrocardiogram and moment of activation isochronal mapping. Physiological Measurement, 28(5), 515-529. doi:10.1088/0967-3334/28/5/006He, B., & Cohen, R. J. (1992). Body surface Laplacian mapping of cardiac electrical activity. The American Journal of Cardiology, 70(20), 1617-1620. doi:10.1016/0002-9149(92)90471-aLu, C.C. and Tarjan, P.P. (2002), “An ultra-high common-mode rejection ratio (CMRR) AC instrumentation amplifier for laplacian electrocardiographic measurement”,Biomedical Instrumentation and Technology, Vol. 33 No. 1, pp. 76-83.Prats-Boluda, G. , Ye-Lin, Y. , Garcia-Breijo, E. , Ibanez, J. and Garcia-Casado, J. (2012), “Active flexible concentric ring electrode for non-invasive surface bioelectrical recordings”,Measurement Science & Technology, Vol. 23 No. 12

    Inexpensive Measuring System for the Characterization of Organic Transistors

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    [EN] A measuring module has been specifically designed for the electrical characterization of organic semiconductor devices such as organic field effect transistors (OFETs) and organic electrochemical transistors (OECTs) according to the IEEE 1620-2008 standard. This device has been tested with OFETs based on 6,13-bis(triisopropylsilylethinyl) pentacene (TIPS-pentacene). The measuring system has been constructed using a NI-PXIe-1073 chassis with integrated controller and two NI-PXI-4132 programmable high-precision source measure units (SMUs) that offer a four-quadrant +/- 100V output, with resolution down to 10 pA. LabVIEW (TM) has been used to develop the appropriate program. Most of the main OFET parameters included in the IEEE 1620 standard can be measured by means of this device. Although nowadays expensive devices for the characterization of Si-based transistors are available, devices for the characterization of organic transistors are not yet widespread in the market. Fabrication of a specific and flexible module that can be used to characterize this type of transistors would provide a powerful tool to researchers.All financial support from the Spanish Government and FEDER funds (MAT2015-64139-C4-3-R (MINECO/FEDER)) and the Generalitat Valenciana (GVA funds) (AICO/2015/103) is gratefully acknowledged.Pérez Fuster, C.; Lidon-Roger, JV.; Contat-Rodrigo, L.; Garcia-Breijo, E. (2018). Inexpensive Measuring System for the Characterization of Organic Transistors. Journal of Sensors. 2018:1-9. https://doi.org/10.1155/2018/4286894S19201

    Interconversion algorithm between mechanical and dielectric relaxation measurements for acetate of cis- and trans-2-phenyl-5-hydroxymethyl-1,3-dioxane

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    The dielectric and mechanical spectroscopies of acetate of cis- and trans-2-phenyl-5-hydroxymethyl-1,3- dioxane are reported in the frequency domain from 10−2 to 106 Hz. This ester has been selected in this study for its predominant á relaxation with regard to the â relaxation, which can be neglected. This study consists of determining an interconversion algorithm between dielectric and mechanical measurements, given by using a relation between rotational and translational complex viscosities. These important viscosities were obtained from measures of the dielectric complex permittivity and by dynamic mechanical analysis, respectively. The definitions of rotational and translational viscosities were evaluated by means of fractional calculus, by using the fit parameters of theHavriliak-Negami empirical model obtained in the dielectric and mechanical characterization of the á relaxation. This interconversion algorithm is a generalization of the break of the Stokes-Einstein-Debye relationship. It uses a power law with an exponent defined as the shape factor, which modifies the translational viscosity. Two others factors are introduced for the interconversion, a shift factor, which displaces the translational viscosity in the frequency domain, and a scale factor, which makes equal values of the two viscosities. In this paper, the shape factor has been identified as the relation between the slopes of the moduli of the complex viscosities at higher frequency. This is interpreted as the degree of kinetic coupling between the molecular rotation and translational movements. Alternatively, another interconversion algorithm has been expressed by means of dielectric and mechanical moduli.The authors thank Professor Niels Boye Olsen and Jeppe C. Dyre from Roskilde Universitetcenter (Denmark) for dielectric and mechanical measurements. This work was supported by DGAPA-UNAM Projects No. IG-100315, SEP-CONACYT 154626, M.J.S. gratefully acknowledge the CICYT for grant MAT2012-3383.García Bernabé, A.; Lidon-Roger, JV.; Sanchis Sánchez, MJ.; Díaz Calleja, R.; Del Castillo, LF. (2015). Interconversion algorithm between mechanical and dielectric relaxation measurements for acetate of cis- and trans-2-phenyl-5-hydroxymethyl-1,3-dioxane. Physical Review E. 92(4). https://doi.org/10.1103/PhysRevE.92.042307S924Gemant, A. (1935). The conception of a complex viscosity and its application to dielectrics. Transactions of the Faraday Society, 31, 1582. doi:10.1039/tf9353101582DiMarzio, E. A., & Bishop, M. (1974). Connection between the macroscopic electric and mechanical susceptibilities. The Journal of Chemical Physics, 60(10), 3802-3811. doi:10.1063/1.1680822Bird, R. B., & Giacomin, A. J. (2012). Who conceived the «complex viscosity»? 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Fractional Stokes-Einstein and Debye-Stokes-Einstein Relations in a Network-Forming Liquid. Physical Review Letters, 97(5). doi:10.1103/physrevlett.97.055901Fujara, F., Geil, B., Sillescu, H., & Fleischer, G. (1992). Translational and rotational diffusion in supercooled orthoterphenyl close to the glass transition. Zeitschrift f�r Physik B Condensed Matter, 88(2), 195-204. doi:10.1007/bf01323572Glotzer, S. C., Novikov, V. N., & Schrøder, T. B. (2000). Time-dependent, four-point density correlation function description of dynamical heterogeneity and decoupling in supercooled liquids. The Journal of Chemical Physics, 112(2), 509-512. doi:10.1063/1.480541Nee, T., & Zwanzig, R. (1970). Theory of Dielectric Relaxation in Polar Liquids. The Journal of Chemical Physics, 52(12), 6353-6363. doi:10.1063/1.1672951Saiz, E., Riande, E., Díaz-Calleja, R., & Guzmán, J. (1997). 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    Presentation, care and outcomes of patients with NSTEMI according to World Bank country income classification: the ACVC-EAPCI EORP NSTEMI Registry of the European Society of Cardiology.

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    Cohort profile: the ESC EURObservational Research Programme Non-ST-segment elevation myocardial infraction (NSTEMI) Registry.

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    Cohort profile: the ESC EURObservational Research Programme Non-ST-segment elevation myocardial infraction (NSTEMI) Registry

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    Aims The European Society of Cardiology (ESC) EURObservational Research Programme (EORP) Non-ST-segment elevation myocardial infarction (NSTEMI) Registry aims to identify international patterns in NSTEMI management in clinical practice and outcomes against the 2015 ESC Guidelines for the management of acute coronary syndromes in patients presenting without ST-segment-elevation. Methods and results Consecutively hospitalised adult NSTEMI patients (n = 3620) were enrolled between 11 March 2019 and 6 March 2021, and individual patient data prospectively collected at 287 centres in 59 participating countries during a two-week enrolment period per centre. The registry collected data relating to baseline characteristics, major outcomes (inhospital death, acute heart failure, cardiogenic shock, bleeding, stroke/transient ischaemic attack, and 30-day mortality) and guideline-recommended NSTEMI care interventions: electrocardiogram pre- or in-hospital, prehospitalization receipt of aspirin, echocardiography, coronary angiography, referral to cardiac rehabilitation, smoking cessation advice, dietary advice, and prescription on discharge of aspirin, P2Y12 inhibition, angiotensin converting enzyme inhibitor (ACEi)/angiotensin receptor blocker (ARB), beta-blocker, and statin. Conclusion The EORP NSTEMI Registry is an international, prospective registry of care and outcomes of patients treated for NSTEMI, which will provide unique insights into the contemporary management of hospitalised NSTEMI patients, compliance with ESC 2015 NSTEMI Guidelines, and identify potential barriers to optimal management of this common clinical presentation associated with significant morbidity and mortality
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